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The 4th edition of this conference aims to bring scientists from the whole world to share their recent discoveries on sustainable catalysis arising from molecular metal complexes, including their heterogeneous applications. Clean processes leading to complex molecules and molecular materials; biomass transformations into useful industrial intermediates; polymerization catalysts and biodegradable polymers; catalysts for energy economy or energy generation will be presented. The art of organometallic catalysis lies at the heart of this conference. Its impact on life sciences and material sciences will also be prominently featured.