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The SPIG 2020 follows a longtime tradition initiated almost 60 years ago. The Conference covers a wide range of topics from fundamental studies to applications of ionized gases. The 4th workshop on X-ray and VUV Interaction with Biomolecules in Gas Phase (4th XiBiGP), organized in collaboration with the SOLEIL synchrotron (France) will be associated to the conference. The program of the SPIG2020 will consist of Plenary Invited Lectures, Topical Invited Lectures, Progress Reports and Contributed Papers (poster presentations), as well as XiBiGP workshop lectures . A number of parallel and poster sessions will provide an opportunity for junior scientists to present their work.