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Electron dynamics governs a wide range of important effects in nanoscience. Nanoclusters, as important testbed systems for exploring and developing quantum size effects, novel materials, and reaction pathways, exhibit a range of phenomena which are highly sensitive to electron mobility, response, transfer, emission and attachment, direct and exchange interactions, correlations, etc. The aim of the present workshop is to bring together researchers in adjacent fields in order to examine recent and future developments and to enhance the connection between different branches of research. To keep the discussion focused, it will concentrate on free clusters and related systems.